Oxidative Addition of Pseudohalogen to [P(OPh)3]4Ni
نویسندگان
چکیده
Z. Naturforsch. 38b, 1069-1071 (1983); received May 13, 1983 Pseudohalogens, IR Spectra, Nickel The title compound reacts with cyanogen halides, XCN (X = Br or I) to give the complexes L2(X)(CN)Ni (L = P(OPh)3, X = Br or I). The oxidative addition of (SCN)2 and (SeCN)2 to the same compound results in the formation of L2Ni(XCN)2 (X = S or Se). All the complexes have been characterized by elemental analysis, and IR, iH NMR and electronic spectra.
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